L-MENTHYL ACETATE
- NameL-MENTHYL ACETATE
- CAS16409-45-3
- Purity99%
Product Details
Manufacturer supply high quality L-MENTHYL ACETATE 16409-45-3 with ISO standards
- Molecular Formula:C12H22O2
- Molecular Weight:198.305
- Vapor Pressure:0.0707mmHg at 25°C
- Melting Point:<25 °C
- Refractive Index:n20/D 1.447(lit.)
- Boiling Point:229.124 °C at 760 mmHg
- Flash Point:92.222 °C
- PSA：26.30000
- Density:0.927 g/cm3
- LogP:3.01030
L-MENTHYL ACETATE(Cas 16409-45-3) Usage
|
Preparation |
By reacting acetic anhydride with menthol in the presence of anhydrous sodium acetate. |
|
Biochem/physiol Actions |
Taste at 25 ppm |
|
Safety Profile |
Mildly toxic by ingestion. A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. |
|
Taste threshold values |
Taste characteristics at 10 ppm: tea-like, cooling and fruity |
InChI:InChI=1/C12H22O2/c1-8(2)11-6-5-9(3)7-12(11)14-10(4)13/h8-9,11-12H,5-7H2,1-4H3/t9-,11+,12-/m0/s1
16409-45-3 Relevant articles
Solvent-free Acetylation Procedure
Bhat, Sujata V.,Gupta, Manisha O.,Yadav, Jyoti K.,Vaze, Kedar R.
, p. 590 - 594 (2021/10/07)
-
A Method For Preparing (Meth)Acrylic Acid Ester Based Compound
-
Paragraph 0071-0072, (2021/05/07)
The invention relates to a method for pr...
IrIII-Catalyzed direct syntheses of amides and esters using nitriles as acid equivalents: A photochemical pathway
Talukdar, Ranadeep
supporting information, p. 5303 - 5308 (2020/04/17)
An unprecedented IrIII[df(CF3)ppy]2(dtbb...
Continuous-Flow Chemo and Enzymatic Synthesis of Monoterpenic Esters with Integrated Purification
Adarme, Carlos A.A.,Le?o, Raquel A.C.,de Souza, Stefania P.,Itabaiana, Ivaldo,de Souza, Rodrigo O.M.A.,Rezende, Claudia M.
, p. 39 - 46 (2018/05/22)
Monoterpenic esters are very important f...
16409-45-3 Process route
-
-
89-78-1
menthol
-
-
108-24-7
acetic anhydride
-
-
89-48-5,2230-87-7,2552-91-2,2623-23-6,5157-89-1,16409-45-3,20777-36-0,20777-45-1,29066-34-0,42241-42-9,50539-17-8,55058-46-3,79199-84-1,146502-80-9
2-isopropyl-5-methylcyclohexyl acetate
| Conditions | Yield |
|---|---|
|
With
lithium perchlorate;
at 25 ℃;
for 22h;
|
98% |
|
With
silica gel;
for 0.05h;
Microwave irradiation;
neat (no solvent);
|
98% |
|
With
SBA-15-Ph-Pr-SO3H;
at 20 ℃;
for 0.416667h;
|
98% |
|
4-N,N-dimethylaminopyridinium saccharinate;
at 25 ℃;
Product distribution / selectivity;
|
98% |
|
With
C12H8N2*2CH4O3S;
at 30 ℃;
for 2h;
|
98% |
|
With
poly(N,N'-dibromo-N-ethylnaphthyl-2,7-sulfonamide);
In
neat (no solvent);
at 20 ℃;
for 0.5h;
|
97% |
|
With
poly(4-vinylpyridine) supported copper(II) oxide nanoparticles;
In
neat (no solvent);
at 20 ℃;
for 0.05h;
chemoselective reaction;
|
95% |
|
With
lanthanum(III) nitrate;
at 20 ℃;
for 0.25h;
|
94% |
|
With
1-butyl-3-methylimidazolium tetrachloridoferrate(III);
at 20 ℃;
for 1.16667h;
Ionic liquid;
|
94% |
|
With
rice husk ash;
at 80 ℃;
for 1h;
Green chemistry;
|
93% |
|
With
20CuO-ZnO nanocatalyst;
In
dichloromethane;
at 20 ℃;
for 1h;
Green chemistry;
|
89% |
|
With
benzyltriphenylphosphonium tribromide;
In
chloroform;
for 0.216667h;
Reflux;
|
87% |
|
With
camphor-10-sulfonic acid; Graphite;
In
neat (no solvent);
at 20 ℃;
for 0.5h;
|
82% |
|
With
1H-imidazole;
at 20 ℃;
for 24h;
Green chemistry;
|
75% |
|
magnesium bromide;
In
dichloromethane;
at 20 ℃;
for 3h;
|
72% |
|
With
pyridine;
In
dichloromethane;
|
|
|
With
bismuth(lll) trifluoromethanesulfonate;
at 0 ℃;
for 1.5h;
|
97 % Chromat. |
|
With
sulfonated ordered mesoporous carbon (CMK-5-SO3H);
In
neat (no solvent);
at 20 ℃;
for 0.166667h;
Green chemistry;
|
98 %Chromat. |
|
With
cesium 12-tungstophosphate;
at 20 ℃;
for 0.5h;
Time;
Catalytic behavior;
Green chemistry;
|
|
|
With
immobilized enzyme Novozym 435?;
at 150 ℃;
Enzymatic reaction;
|
-
-
108-05-4,9003-20-7
vinyl acetate
-
-
89-78-1
menthol
-
-
89-48-5,2230-87-7,2552-91-2,2623-23-6,5157-89-1,16409-45-3,20777-36-0,20777-45-1,29066-34-0,42241-42-9,50539-17-8,55058-46-3,79199-84-1,146502-80-9
2-isopropyl-5-methylcyclohexyl acetate
| Conditions | Yield |
|---|---|
|
iodine;
at 20 ℃;
for 4.5h;
|
94% |
|
With
2,2'-(phenylimino)bis[ethanol]; diethylzinc;
In
hexane; toluene;
at 20 ℃;
for 24h;
|
91% |
|
With
pseudomonas fuorescens lipase immobilized on multiwall carbon nano-tubes;
at 50 ℃;
for 12h;
Green chemistry;
|
44% |
16409-45-3 Upstream products
-
108-24-7
acetic anhydride
-
1181819-05-5
menthol
-
89-78-1
[1-α]-5-methyl-2-[1-methylethyl]-cyclohexanol
-
108-05-4
vinyl acetate
16409-45-3 Downstream products
-
89-78-1
menthol
-
2216-51-5
(-)-menthol
-
15356-60-2
(1S,2R,5S)-(+)-menthol
-
491-07-6
(+/-)-menthone
Related products
-
2,2'-[(6-chloro-1,3,5-triazine-2,4-diyl)diimino]bisethanolCAS：54581-55-4
-
2-HYDROXYPROPYL ACRYLATECAS：999-61-1
-
TRIMETHYLTHIOUREACAS：2489-77-2
-
PIPERAZINE-2-CARBOXAMIDECAS：84501-64-4