2-METHYL-1-(PYRIDIN-2-YL)PROPAN-1-ONE
- Name 2-METHYL-1-(PYRIDIN-2-YL)PROPAN-1-ONE
- CAS 59576-30-6
- Purity 99%
Product Details
Buy high quality and low price 2-METHYL-1-(PYRIDIN-2-YL)PROPAN-1-ONE 59576-30-6 now
- Molecular Formula: C9H11 N O
- Molecular Weight: 149.192
- Vapor Pressure: 0.098mmHg at 25°C
- Melting Point: 179-180 °C
- Boiling Point: 223.1°C at 760 mmHg
- PKA: 3.04±0.10(Predicted)
- Flash Point: 93.8°C
- PSA： 29.96000
- Density: 1.01g/cm3
- LogP: 1.92030
2-METHYL-1-(PYRIDIN-2-YL)PROPAN-1-ONE(Cas 59576-30-6) Usage
|
Synthesis Reference(s) |
Synthetic Communications, 19, p. 2489, 1989 DOI: 10.1080/00397918908052651 |
InChI:InChI=1/C9H11NO/c1-7(2)9(11)8-5-3-4-6-10-8/h3-7H,1-2H3
59576-30-6 Relevant articles
Site-Selective Pd-Catalyzed C(sp3)?H Arylation of Heteroaromatic Ketones
Kudashev, Anton,Baudoin, Olivier
supporting information, p. 17688 - 17694 (2021/11/16)
A ligand-controlled site-selective C(sp3...
One-Pot Conversion of Allylic Alcohols to α-Methyl Ketones via Iron-Catalyzed Isomerization-Methylation
Latham, Daniel E.,Polidano, Kurt,Williams, Jonathan M. J.,Morrill, Louis C.
supporting information, p. 7914 - 7918 (2019/10/16)
A one-pot iron-catalyzed conversion of a...
Pd-Catalyzed Alkylation of (Iso)quinolines and Arenes: 2-Acylpyridine Compounds as Alkylation Reagents
Wu, Qingsong,Han, Shuaijun,Ren, Xiaoxiao,Lu, Hongtao,Li, Jingya,Zou, Dapeng,Wu, Yangjie,Wu, Yusheng
supporting information, p. 6345 - 6348 (2018/10/20)
The first Pd-catalyzed alkylation of (is...
Iron-Catalyzed Methylation Using the Borrowing Hydrogen Approach
Polidano, Kurt,Allen, Benjamin D. W.,Williams, Jonathan M. J.,Morrill, Louis C.
, p. 6440 - 6445 (2018/07/25)
A general iron-catalyzed methylation has...
59576-30-6 Process route
-
-
100-70-9,1232006-36-8
2-Cyanopyridine
-
-
920-39-8
isopropylmagnesium bromide
-
-
59576-30-6
2-methyl-1-(pyridin-2-yl)propan-1-one
| Conditions | Yield |
|---|---|
|
2-Cyanopyridine; isopropylmagnesium bromide;
In
diethyl ether;
at -15 - 20 ℃;
for 3h;
With
hydrogenchloride; water;
In
diethyl ether;
at 20 ℃;
for 0.25h;
|
84%
|
|
In
diethyl ether;
for 0.5h;
|
80%
|
|
In
methanol; diethyl ether; water;
at -20 ℃;
|
54%
|
|
|
-
-
102439-95-2
α-isopropyl(2-pyridyl)methanol
-
-
59576-30-6
2-methyl-1-(pyridin-2-yl)propan-1-one
| Conditions | Yield |
|---|---|
|
With
tert.-butylhydroperoxide; tetrabutyl-ammonium chloride; sodium carbonate;
copper dichloride; 2,2′‐biquinoline‐4,4′‐dicarboxylic acid dipotassium salt;
In
water;
at 40 ℃;
for 48h;
|
100%
|
|
With
tert.-butylhydroperoxide; copper(II) choride dihydrate; sodium carbonate; 2,2′‐biquinoline‐4,4′‐dicarboxylic acid dipotassium salt;
In
water;
at 20 ℃;
|
59576-30-6 Upstream products
-
100-70-9
2-Cyanopyridine
-
920-39-8
isopropylmagnesium bromide
-
1122-62-9
2-acetylpyridine
-
74-88-4
methyl iodide
59576-30-6 Downstream products
-
31595-32-1
2,2-dimethyl-1-pyridin-2-yl-propan-1-one
-
864429-01-6
4-Methyl-benzenesulfinic acid [2-methyl-1-pyridin-2-yl-prop-(E)-ylidene]-amide
-
138175-25-4
(R)-2-Methyl-1-pyridin-2-yl-propylamine
-
144852-18-6
(S)-2-methyl-1-(pyridin-2-yl)propan-1-amine
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